固体除湿空调系统可由低品位能源驱动且无污染，吸附剂是固体除湿空调系统的核心。为解决传统固体除湿材料除湿效率低，除湿能耗高等问题，本文制备了具有高水蒸气吸附量、吸附/脱附速度快并且水热稳定性好的负载型改性硅胶复合除湿材料和金属有机框架材料/陶瓷纤维纸除湿材料两种除湿材料。采用氮气吸附-解吸法（BET）、扫描电镜（SEM）、X射线衍射（PXRD）和热重分析（TG）对除湿材料进行了表征和分析。研究了两种除湿材料的动态除湿性能和除湿再生循环性能；并将金属有机框架材料/陶瓷纤维纸除湿材料制备成蜂窝固体除湿器，通过自主搭建试验台对除湿器进行性能研究。
   实验研究了负载型改性硅胶复合除湿材料在中高湿度下的除湿性能。结果表明：当制备条件为50 ml水、30 ml硅溶胶、浸渍时间为10 min时，所制备的Mg-B-Ca(25%)除湿性能最好，相比传统硅胶除湿量提高了3.2倍，且具有良好的再生性能。吸附动力学显示：水蒸气在Mg-B-Ca(25%)上的扩散系数为31.45~45.1×10-10 cm2/s（温度条件为20~40 ℃），吸附活化能为13.72 kJ/mol，对水蒸气的吸附遵循伪一级动力模型。
    实验研究了金属有机框架材料/陶瓷纤维纸（MIL-101/CFP）除湿材料在中高湿度下的除湿性能。结果表明：当涂覆率C为70%时，金属有机框架材料/陶瓷纤维纸除湿材料（MIL-101/CFP-70）具有高的平衡除湿能力且能实现高的除湿率；和吸附量比传统硅胶吸附材料高100 mg/g，且具有很好的水热稳定性。吸附动力学显示：水蒸气在MIL-101/CFP-70上的扩散系数为1.71~2.41×10-10 cm2/s（温度条件为20~50 ℃），其吸附活化能为9.71 kJ/mol，且水蒸气的吸附遵循伪一级动力模型。
     应用金属有机框架材料/陶瓷纤维纸（MIL-101/CFP-70）制备了蜂窝固体除湿器，并在不同实验工况下进行了性能测试。结果表明：蜂窝固体除湿器最佳吸附-脱附时间为8min时，除湿效率和除湿量最大；当相对湿度处于70~90%时，再生温度在50~70 ℃时，除湿性能系数为0.83~0.95，且具有很高的除湿效率和除湿量；采取预冷的方式降低处理空气的进口温度可以提高除湿系统的DCOP。当吸附-脱附时间为8 min、处理风速为2 m/s、再生风速为2 m/s且再生温度为70 ℃时，除湿器具有最佳的综合性能表现，其除湿效率为44.70%，单位质量除湿量为4.90 kg/(kg·h)，除湿性能系数为0.95。

~Solid dehumidification air conditioning system can be driven by low grade energy and no pollution. Adsorbent is the core of solid dehumidification air conditioning system. In order to solve the problems of low dehumidification efficiency and high dehumidification energy consumption of traditional solid dehumidification materials, a loaded modified silica gel composite dehumidifier material with high water vapor adsorption capacity, fast adsorption/desorption speed and good hydrothermal stability and a metal organic frame material/ceramic fiber paper dehumidification material two dehumidifying materials were prepared. Nitrogen adsorption-desorption (BET), scanning electron microscopy (SEM), x-ray diffraction (PXRD) and thermogravimetric analysis (TG) were used to characterize and analyze the dehumidifying materials. The two dehumidifying materials dynamic dehumidification performance and the recycling performance of dehumidification were studied, and the metal organic frame material/ceramic fiber paper dehumidifier was prepared into honeycomb solid dehumidifier, and the performance of dehumidifier is studied by self-built test bed.
The dehumidification performance of loaded modified silica gel composite dehumidifier under medium and high humidity was studied experimentally. The results show that when the preparation condition is 50 ml of water, 30 ml silicone sol and impregnation time is 10 min, the prepared Mg-B-Ca(25%) has the best dehumidification performance, which is 3.2 times higher than the amount of traditional silicone dehumidification, and has good regeneration performance. The adsorption kinetics show that the diffusion coefficient of water vapor on Mg-B-Ca(25%) is 31.45~45.1×10-10 cm2/s (Temperature conditions 20~40 ℃), and the adsorption activation energy can be 13.72 kJ/mol, and the adsorption of water vapor follows a pseudo-first-stage dynamic model.
Dehumidification properties of metal organic skeleton material/ceramic fiber paper (MIL-101/CFP) dehumidification material at medium and high humidity are studied experimentally. The results show that when the coating rate is 70, the metal organic frame material/ceramic fiber paper dehumidification material (MIL-101/CFP-70) has high equilibrium dehumidification ability and can achieve high dehumidification rate. The saturated adsorption capacity is 100 mg/g, higher than that of traditional silica gel adsorption material and has good hydrothermal stability. The adsorption kinetics showed that the diffusion coefficient of water vapor on the MIL-101/CFP-70 was 1.71~2.41×10-10 cm2/s(Temperature conditions 20~50 ℃), the adsorption activation energy was 9.71 kJ/mol, and the adsorption of water vapor followed the pseudo-first-order dynamic model.
Honeycomb solid dehumidifier was prepared using metal organic frame material/ceramic fiber paper (MIL-101/CFP-70) and its performance was tested under different experimental conditions. As a result, when the optimum adsorption-desorption time of honeycomb solid dehumidifier is 8 min, the dehumidification efficiency and dehumidification capacity are maximum; When the relative humidity is 70~90%, the regeneration temperature is 50~70 ℃, DCOP values range from 0.83~0.95, and it has high dehumidification efficiency and dehumidification capacity; Decreasing the inlet temperature of air treated by precooling can increase the DCOP. When the adsorption-desorption time is 8 min, the treatment wind speed is 2 m/s, the regeneration wind speed is 2 m/s and the regeneration temperature is 70 ℃, the dehumidifier have the best comprehensive performance, The dehumidification efficiency is 44.7% and the unit mass dehumidification is 4.90 kg/(kg·h) and DCOP is 0.95.

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