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论文中文题名：	a液a态aCaOa2a酸a化a增a透a煤a岩a及a孔a隙a结a构a重a构a机a制a实a验a研a究a*
姓名：	王文
学号：	a1a8a2a2a0a0a8a9a0a2a4a
保密级别：	a公a开a*
论文语种：	acahaia
学科代码：	a0a8a3a7a0a0a*
学科名称：	a工a学a* a-a a安a全a科a学a与a工a程a
学生类型：	a硕a士a*
学位级别：	a工a学a硕a士a*
学位年度：	a2a0a2a1a*
培养单位：	a西a安a科a技a大a学a*
院系：	安全科学与工程学院
专业：	安全科学与工程
研究方向：	a矿a井a瓦a斯a灾a害a治a理a*
第一导师姓名：	文虎
第一导师单位：	西安科技大学
论文提交日期：	a2a0a2a1a-a0a6a-a1a8a*
论文答辩日期：	a2a0a2a1a-a0a6a-a0a2a*
论文外文题名：	aEaxapaearaiamaeanataala* asatauadaya aoafa* alaiaqauaiada* aCaOa2a aacaiadaiafaiacaataiaoana aanataiaraeafalaeacataiaoana* acaoaala* aanada apaoaraea* asatarauacatauaraea araeacaoanasatarauacataiaoana* amaeacahaanaiasama
论文中文关键词：	液态CO2 ; 溶浸 ; 酸化 ; 孔隙结构 ; 重构机制
论文外文关键词：	Liquid CO2 ; Leaching ; Acidification ; Pore structure ; Reconstruction mechanism Thesis :Application Study
论文中文摘要：	︿ a<apa>a液a态aCaOa<asauaba>a2a<a/asauaba>a压a裂a煤a层a增a透a技a术a在a治a理a矿a井a瓦a斯a灾a害a、a提a高a煤a层a气a产a量a的a同a时a可a以a缓a解a温a室a效a应a，a逐a渐a成a为a研a究a热a点a。a本a文a基a于a液a态aCaOa<asauaba>a2a<a/asauaba>a本a身a低a温a、a高a压a、a非a极a性a及a相a变a后a遇a水a酸a化a等a特a性a，a通a过a搭a建a液a态aCaOa<asauaba>a2a<a/asauaba>a溶a浸a-a酸a化a煤a体a实a验a平a台a，a先a后a开a展a液a态aCaOa<asauaba>a2a<a/asauaba>a溶a浸a煤a体a及a酸a化a煤a体a实a验a，a并a采a用a氮a吸a附a、aXaRaDa、aXaRaFa、aIaCaPa-aOaEaSa、aFaTaIaRa、aSaEaMa-aEaDaSa等a一a系a列a测a试a手a段a研a究a液a态aCaOa<asauaba>a2a<a/asauaba>a注a入a煤a层a后a在a液a相a阶a段a及a酸a化a阶a段a与a煤a体a的a矿a物a、a有a机a质a相a互a作a用a及a煤a体a孔a隙a结a构a重a构a过a程a机a制a，a得a到a以a下a结a论a：a<a/apa>a a* a<apa>a通a过a测a定a煤a中a矿a物a含a量a、a煤a体a与a反a应a水a样a的a元a素a含a量a、apaHa等a参a数a并a分a析a了a矿a物a演a化a机a制a，a结a果a表a明a：a液a态aCaOa<asauaba>a2a<a/asauaba>a溶a浸a对a煤a中a矿a物a影a响a微a弱a，a主a要a由a于a液a态aCaOa<asauaba>a2a<a/asauaba>a低a温a损a伤a与a机a械a迁a移a造a成a煤a体a矿a物a的a部a分a崩a塌a以a及a微a量a迁a移a；a液a态aCaOa<asauaba>a2a<a/asauaba>a酸a化a后a多a数a矿a物a含a量a显a著a降a低a，a且a对a压a力a较a为a敏a感a。a液a态aCaOa<asauaba>a2a<a/asauaba>a酸a化a主a要a导a致a煤a体a发a生a溶a蚀a反a应a、a转a化a与a沉a淀a、a粘a土a的a水a化a膨a胀a作a用a，a其a中a溶a蚀a反a应a较a强a烈a。a无a烟a煤a与a长a焰a煤a中a碳a酸a盐a含a量a在a溶a蚀a作a用a下a降a幅a最a大a，a其a次a为a伊a利a石a，a石a英a、a叶a腊a石a及a金a红a石a含a量a变a化a较a微a弱a。a压a力a越a大a，a反a应a水a样a的aHa<asauapa>a+a<a/asauapa>a消a耗a越a快a，a煤a体a中a矿a物a组a分a溶a蚀a反a应a越a强a烈a，a导a致a各a组a分a元a素a溶a出a量a及a迁a移a率a越a大a，a其a中a无a烟a煤a与a长a焰a煤a中aCaa元a素a溶a出a量a及a迁a移a率a均a最a大a，a这a主a要a是a碳a酸a盐a的a溶a蚀a造a成a。a<a/apa>a* a* a<apa>a通a过a测a定a煤a中a有a机a物a的a官a能a团a结a构a含a量a并a分a析a其a演a化a机a制a，a结a果a表a明a：a液a态aCaOa<asauaba>a2a<a/asauaba>a溶a浸a及a酸a化a过a程a有a机a质a官a能a团a结a构a含a量a受a到a溶a胀a、a溶a解a、a萃a取a、a键a解a离a反a应a、a加a成a反a应a、a取a代a反a应a等a共a同a控a制a。a液a态aCaOa<asauaba>a2a<a/asauaba>a溶a浸a后a，a除a1aHa外a无a烟a煤a与a长a焰a煤a芳a香a结a构a2aHa、a3aHa、a5aHa官a能a团a相a对a含a量a整a体a增a大a；a脂a肪a醚a、a芳a香a醚a及a羰a基aCa=aOa等a非a极a性a或a弱a极a性a官a能a团a受a到a萃a取a作a用a后a含a量a减a少a；a键a解a离a反a应a破a坏a了a部a分a芳a香a结a构aCa=aCa结a构a并a使a脂a肪a烃a结a构a大a量a脱a落a，aOaHa-aOa含a量a、a自a缔a合a羟a基a氢a键aOaHa-aOaHa含a量a均a减a少a。a液a态aCaOa<asauaba>a2a<a/asauaba>a酸a化a后a，a无a烟a煤a各a组a分a芳a香a结a构a含a量a进a一a步a增a大a；a长a焰a煤a1aHa、a3aHa、a5aHa含a量a增a大a，a2aHa结a构a含a量a减a少a；a两a种a煤a样a脂a肪a醚a、a芳a香a醚a及a羰a基aCa=aOa等a非a极a性a或a弱a极a性a官a能a团a含a量a依a然a受a到a萃a取a作a用a减a少a，a-aCaOaOaHa结a构a含a量a大a幅a提a高a，a脂a肪a烃a结a构a含a量a整a体a进a一a步a减a少a，a羟a基a官a能a团a含a量a整a体a明a显a增a大a。a此a外a，a两a种a煤a样a在a液a态aCaOa<asauaba>a2a<a/asauaba>a溶a浸a、a酸a化a后a芳a香a性a与a缩a合a度a均a得a到a提a升a，a且a液a态aCaOa<asauaba>a2a<a/asauaba>a酸a化a后a芳a香a性a与a缩a合a度a整a体a均a表a现a出a随a着a压a力a增a大a而a增a大a的a趋a势a。a<a/apa>a* a* a<apa>a通a过a测a定a煤a的a孔a隙a结a构a参a数a并a结a合a矿a物a组a分a、a有a机a物a演a化a机a制a分a析a孔a隙a结a构a重a组a机a制a，a结a果a表a明a：a液a态aCaOa<asauaba>a2a<a/asauaba>a溶a浸a作a用a后a无a烟a煤a与a长a焰a煤a比a表a面a积a均a减a小a，a微a孔a数a量a减a少a且a长a焰a煤a减a少a幅a度a大a于a无a烟a煤a，a孔a径a峰a值a也a向a大a孔a径a方a向a转a移a，a两a种a煤a的a大a孔a、a中a孔a、a微a孔a孔a容a均a明a显a提a升a。a通a过a分a析a认a为a，a低a温a导a致a部a分a含a化a合a态a水a分a的a矿a物a崩a塌a并a有a利a于a形a成a裂a缝a增a大a孔a隙a连a通a性a，a但a矿a物a与a煤a的a颗a粒a发a生a机a械a迁a移a一a方a面a使a煤a体a表a面a未a被a打a开a的a孔a隙a受a到a冲a击a、a剥a离a作a用a后a被a打a开a并a形a成a大a孔a，a但a也a有a部a分a大a孔a被a发a生a迁a移a的a颗a粒a物a堵a塞a；a液a态aCaOa<asauaba>a2a<a/asauaba>a溶a浸a后a无a烟a煤a与a长a焰a煤a的a微a孔a数a量a减a少a主a要a是a由a于a煤a基a质a的a溶a胀a及a芳a环a缩a合a度a的a提a高a使a得a分a子a间a隙a变a小a、a有a序a度a提a高a导a致a，a而a受a到a萃a取a的a非a极a性a小a分a子a、a官a能a团a的a溶a出a造a成a微a孔a孔a容a的a增a大a；a液a态aCaOa<asauaba>a2a<a/asauaba>a酸a化a后a，a无a烟a煤a与a长a焰a煤a比a表a面a积a均a整a体a增a大a，a孔a径a峰a值a区a间a又a向a微a孔a方a向a转a移a，a无a烟a煤a微a孔a、a大a孔a孔a容a有a明a显a的a提a高a，a中a孔a孔a容a有a所a降a低a；a长a焰a煤a中a孔a和a大a孔a孔a容a增a大a且a表a现a出a随a着a压a力a增a大a而a增a大a的a趋a势a。a此a外a，a溶a浸a作a用a导a致a部a分a大a孔a被a堵a塞a，a但a是a经a过a酸a化a作a用a后a这a些a大a孔a又a被a重a新a打a开a。a无a烟a煤a表a面a钾a长a石a形a成a少a量a石a英a沉a淀a，a高a岭a石a与a方a解a石a在a溶a蚀a反a应a导a致a半a封a闭a孔a被a打a开a；a长a焰a煤a由a于a矿a物a分a布a较a为a均a匀a，a酸a化a后a煤a体a表a面a片a状a煤a体a脱a落a且a煤a体a显a著a趋a于a疏a松a、a颗a粒a化a并a形a成a大a量a溶a蚀a孔a与a溶a蚀a碎a屑a，a且a随a着a压a力a的a增a大a，a煤a体a表a面a逐a渐a趋a于a颗a粒a化a。a液a态aCaOa<asauaba>a2a<a/asauaba>a酸a化a后a矿a物a演a化a表a现a为a对a中a孔a、a大a孔a的a增a孔a、a扩a孔a作a用a；a而a无a烟a煤a与a长a焰a煤a微a孔a的a发a育a主a要a原a因a是a由a于a酸a化a过a程a促a进a了a大a分a子a相a的a溶a胀a与a溶a解a过a程a，a溶a胀a与a溶a解a作a用a得a到a加a速a后a大a分a子a相a与a大a分a子a相a之a间a的a无a序a度a提a高a使a得a分a子a间a间a隙a扩a大a、a微a孔a数a量a增a多a的a同a时a孔a容a也a得a到a提a高a；a此a外a，a酸a化a作a用a使a大a量a边a缘a基a团a如a甲a基a、a亚a甲a基a、a脂a肪a醚a、a芳a香a醚a类a以a及a碳a基aCa=aOa结a构a受a到a萃a取a、a脱a落a并a溶a出a，a进a一a步a导a致a微a孔a孔a容a增a大a。a<a/apa>a a* a<apa>a论a文a的a研a究a结a果a可a为a液a态aCaOa<asauaba>a2a<a/asauaba>a压a裂a煤a层a增a产a煤a层a气a提a供a理a论a基a础a和a数a据a支a撑a，a有a学a术a研a究a和a工a程a应a用a价a值a。a<a/apa>a* a* ﹀
论文外文摘要：	︿ a<apa>aLaiaqauaiada aCaOa<asauaba>a2a<a/asauaba>a&anabasapa;afaraacatauaraianaga* acaoaala* asaeaama* aanataia-araeafalaeacataiaoana ataeacahanaoalaoagaya* acaana aalalaeavaiaataea agaraeaeanahaoauasaea* aeafafaeacata* awahaialaea acaoanataraoalalaianaga amaianaea* agaasa adaiasaasataeara* aanada aiamaparaoavaianaga acaoaala* abaeada amaeatahaanaea aparaoadauacataiaoana,a aanada ahaasa agaraadauaalalaya abaeacaoamaea* aa araeasaeaaracaha* ahaoatasapaoata.a* aIana* atahaiasa* apaapaeara,a* abaasaeada aoana* atahaea acahaaraacataearaiasataiacasa aoafa* alaiaqauaiada* aCaOa<asauaba>a2a<a/asauaba>a&anabasapa;aiatasaealafa,a asauacaha* aasa* alaoawa ataeamapaearaatauaraea,a* ahaiagaha* aparaeasasauaraea,a anaoana-apaoalaara aanada awaataeara aacaiadaiafaiacaataiaoana aafataeara apahaasaea acahaanagaea,a abaya* abauaialadaianaga* aana* aeaxapaearaiamaeanataala* apalaatafaoarama* afaoara alaiaqauaiada* aCaOa<asauaba>a2a<a/asauaba>a&anabasapa;alaeaacahaianaga* aanada aacaiadaiafaiacaataiaoana aoafa* acaoaala,a alaiaqauaiada* aCaOa<asauaba>a2a<a/asauaba>a&anabasapa;alaeaacahaianaga* aanada aacaiadaiafaiacaataiaoana aoafa* acaoaala* ahaavaea* abaeaeana* acaararaiaeada aoauata.a* aAa asaearaiaeasa* aoafa* ataeasata* amaeatahaoadasa,a* asauacaha* aasa* anaiataraoagaeana* aadasaoarapataiaoana,a aXaRaDa,a* aXaRaFa,a* aIaCaPa-aOaEaSa,a* aFaTaIaRa* aanada aSaEaMa-aEaDaSa,a* awaearaea* auasaeada* ataoa* asatauadaya atahaea aianataearaacataiaoana abaeatawaeaeana alaiaqauaiada* aCaOa<asauaba>a2a<a/asauaba>a&anabasapa;aanada acaoaala* aata* atahaea alaiaqauaiada* apahaasaea aanada aacaiadaiafaiacaataiaoana asataagaea,a* aasa* awaealala* aasa* atahaea aparaoacaeasasa amaeacahaanaiasama aoafa* apaoaraea* asatarauacatauaraea araeacaoanasatarauacataiaoana* aoafa* acaoaala* abaoadaya.a aTahaea afaoalalaoawaianaga acaoanacalauasaiaoanasa awaearaea* adaraawana:a<a/apa>a* a* a<apa>aBaya amaeaasauaraianaga atahaea amaianaearaala acaoanataeanata aiana* acaoaala,a atahaea aealaeamaeanata acaoanataeanata aoafa* acaoaala* abaoadaya* aanada araeaacataiaoana* awaataeara asaamapalaea,a apaHa* aanada aoatahaeara apaaraamaeataearasa,a atahaea aeavaoalauataiaoana amaeacahaanaiasama aoafa* amaianaearaalasa* awaasa aanaalayazaeada.a aTahaea araeasaualatasa asahaoawa* atahaata* alaiaqauaiada* aCaOa<asauaba>a2a<a/asauaba>a&anabasapa;alaeaacahaianaga* ahaasa alaiatatalaea* aeafafaeacata* aoana* atahaea amaianaearaalasa* aiana* acaoaala* abaoadaya,a awahaiacaha aiasa* amaaianalaya* adauaea ataoa* atahaea apaarataiaala acaoalalaapasaea* aanada ataraacaea amaiagaraataiaoana aoafa* acaoaala* abaoadaya* amaianaearaalasa* acaauasaeada* abaya* alaoawa ataeamapaearaatauaraea adaamaagaea* aanada amaeacahaanaiacaala* amaiagaraataiaoana aoafa* alaiaqauaiada* aCaOa<asauaba>a2a<a/asauaba>a.a aTahaea acaoanataeanata aoafa* amaoasata* amaianaearaalasa* adaeacaraeaasaeada asaiaganaiafaiacaanatalaya aafataeara alaiaqauaiada* aCaOa<asauaba>a2a<a/asauaba>a&anabasapa;aacaiadaiafaiacaataiaoana aanada awaasa asaeanasaiataiavaea ataoa* aparaeasasauaraea.a aTahaea aacaiadaiafaiacaataiaoana aoafa* alaiaqauaiada* aCaOa<asauaba>a2a<a/asauaba>a&anabasapa;amaaianalaya* alaeaadasa ataoa* atahaea adaiasasaoalauataiaoana araeaacataiaoana,a ataraanasafaoaramaataiaoana* aanada aparaeacaiapaiataataiaoana aoafa* acaoaala* aanada atahaea ahayadaraataiaoana aanada aeaxapaanasaiaoana aoafa* acalaaya,a aamaoanaga awahaiacaha atahaea adaiasasaoalauataiaoana araeaacataiaoana* aiasa* asataraoanagaeara.a aCaarabaoanaataea acaoanataeanata aiana* aanataharaacaiataea* aanada alaoanaga-afalaamaea* acaoaala* adaeacaraeaasaeada atahaea amaoasata* adauaraianaga* adaiasasaoalauataiaoana,a* afaoalalaoawaeada* abaya* aialalaiataea,a aqauaarataza,a apayaraoapahayalalaiataea* aanada arauataialaea* acaoanataeanata acahaanagaeada asalaiagahatalaya.a aTahaea ahaiagahaeara* atahaea aparaeasasauaraea,a atahaea afaasataeara* atahaea aHa+a* acaoanasauamapataiaoana aoafa* atahaea araeaacataiaoana* awaataeara asaamapalaea* aiasa,a aanada atahaea asataraoanagaeara* atahaea adaiasasaoalauataiaoana araeaacataiaoana* aoafa* atahaea amaianaearaala acaoamapaoanaeanatasa* aiana* atahaea acaoaala* abaoadaya* aiasa,a araeasaualataianaga aiana* atahaea agaraeaataeara atahaea aealaeamaeanata adaiasasaoalauataiaoana aanada amaoabaialaiataya* aoafa* aeaacaha* acaoamapaoanaeanata.a* aAamaoanaga atahaeama,a atahaea aCaa* aealaeamaeanata adaiasasaoalauataiaoana aanada amaoabaialaiataya* aaraea atahaea alaaragaeasata aiana* atahaea aanataharaacaiataea* aanada alaoanaga-afalaamaea* acaoaala,a awahaiacaha aiasa* amaaianalaya* acaauasaeada* abaya* atahaea adaiasasaoalauataiaoana aoafa* acaarabaoanaataea.a<a/apa>a* a* a<apa>a&anabasapa;a<a/apa>a a* a<apa>aBaya amaeaasauaraianaga atahaea afauanacataiaoanaala* agaraoauapa asatarauacatauaraea acaoanataeanata aoafa* aoaragaanaiaca amaatataeara* aiana* acaoaala* aanada aanaalayazaianaga aiatasa 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